Villarreal came from behind to beat Napoli at the Estadio de la Ceramica and secure their first Champions League victory in eight matches.
The La Liga side had lost their previous seven games in the competition, a run stretching back to a 2-2 draw with Juventus in October 2025.
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They appeared destined for an eighth successive defeat after Napoli defender Amir Rrahmani opened the scoring in the eighth minute. He found space at the far post and converted to give the visitors an early advantage.
Napoli came close to extending their lead in the 22nd minute, but Rasmus Hojlund’s header struck the crossbar.
Villarreal equalised less than a minute later when Georges Mikautadze capitalised on an underhit backpass from Matteo Politano. The goal was Mikautadze’s first in the Champions League this season.
The hosts completed the turnaround in the 25th minute. Uruguay midfielder Santiago Mourino collected the ball at distance and struck a powerful effort beyond Napoli goalkeeper Vanja Milinkovic-Savic.
Villarreal’s victory was confirmed four minutes before full-time when substitute Tani Oluwaseyi produced a composed finish from inside the area.
The result ended Villarreal’s sequence of seven consecutive Champions League defeats. They had already lost 3-2 to Borussia Dortmund on the opening matchday and were at risk of becoming the first Spanish side to suffer eight straight European defeats.
Villarreal will travel to Liverpool on 20 October, with kick-off at 20:00 BST. Napoli host Bodo/Glimt at the same time.
